Sujet d’étude:
- Auto-organisation de copolymères à blocs
- Elaboration de membranes et de film minces nanostructurés
- Caractérisation structurale de matériaux polymères
Après avoir reçu un doctorat en physique (sous la direction du Dr. T. Baron) de l’Université de Grenoble (Joseph Fourier, 2008), et effectué un postdoctorat au Massachusetts Institute of Technology (MIT) avec le professeur C. A. Ross, Karim Aissou est devenu Chercheur au CNRS en 2013. K. A. a été recruté au Laboratoire de Chimie des Polymeres Organiques (LCPO) en tant que Chargé de Recherche pour travailler avec le professeur G. Hadziioannou sur l’auto-assemblage dirigé (DSA) de films minces en copolymère à blocs (BCP). K. A. travaille désormais au sein de l’IEM sur l’auto-assemblage de membranes à base de BCP pour des applications dans les batteries, la filtration, etc.
Le Dr. Karim Aissou a co-signé environs 40 publications et plus de 10 brevets :
ORCID ID : 0000-0002-9236-464X
- Courriel : karim.aissou@umontpellier.fr
46 documents
Articles dans une revue
- Lucie Badouric, Martin Drobek, Jim Cartier, Christophe Charmette, Bertrand Rebière, et al.. Effective Atomic Layer Deposition of palladium coatings for hydrogen separation membranes. Surfaces and Interfaces, 2025, 62, pp.106181. ⟨10.1016/j.surfin.2025.106181⟩. ⟨hal-05081380⟩
- Karim Aissou, Maximilien Coronas, Jason Richard, Erwan Ponsin, Sambhav Vishwakarma, et al.. Ion and Water Transports in Double Gyroid Nanochannels Formed by Block Copolymer Anion Exchange Membranes. Batteries, 2025, 11 (4), pp.126. ⟨10.3390/batteries11040126⟩. ⟨hal-05136703⟩
- Lauran Mama, Johanne Pirkin-Benameur, Vincent Bouad, David Fournier, Patrice Woisel, et al.. Development of Thermo-Responsive and Salt-Adaptive Ultrafiltration Membranes Functionalized with PNIPAM-co-PDMAC Copolymer. Membranes, 2025, 15 (6), pp.164. ⟨10.3390/membranes15060164⟩. ⟨hal-05101187⟩
- Karim Aissou, Maximilien Coronas, Jason Richard, Camille Bakkali-Hassani, Sambhav Vishwakarma, et al.. Lithium iodide transport in double gyroid nanochannels formed by zwitterion‐containing solid polymer electrolytes. Journal of Polymer Science, 2024, 62 (20), pp.4567-4575. ⟨10.1002/pol.20240206⟩. ⟨hal-04772307⟩
- Karim Aissou, Maximilien Coronas, Daniel Hermida-Merino, Eduardo Solano, Didier Cot, et al.. Nanoporous Double-Gyroid Structure from ABC Triblock Terpolymer Thick Films. International Journal of Polymer Science, 2023, 2023, pp.1-9. ⟨10.1155/2023/9598572⟩. ⟨hal-04285166⟩
- Karim Aissou, Muhammad Mumtaz, Daniel Hermida-Merino, Eduardo Solano, Didier Cot, et al.. Square arrays of vertically aligned nanoporous cylinders from a linear ABC triblock terpolymer. Journal of Polymer Science, In press, ⟨10.1002/pol.20230088⟩. ⟨hal-04094125⟩
- Quentin Hanniet, Eddy Petit, Sylvie Calas-Etienne, Pascal Etienne, Karim Aissou, et al.. Rational design of SiBCN microstructures using direct photolithography of patternable preceramic photoresists. Materials & Design, 2022, 223, pp.111234. ⟨10.1016/j.matdes.2022.111234⟩. ⟨hal-04038258⟩
- Hana Bouzit, Felix Krusch, Daniel Hermida-Merino, Eduardo Solano, Didier Cot, et al.. Double Stimuli-Responsive Perforated Lamellar Structure Formed by Linear ABC Triblock Terpolymer Monoliths. Journal of Polymer Science, 2022, ⟨10.1002/pol.20220264⟩. ⟨hal-03715575⟩
- Dan-Dan Su, Karim Aissou, Yan Zhang, Virginie Gervais, Sebastien Ulrich, et al.. Squalene–polyethyleneimine–dynamic constitutional frameworks enhancing the enzymatic activity of carbonic anhydrase. Catalysis Science & Technology, 2022, 12 (10), pp.3094-3101. ⟨10.1039/d1cy02290c⟩. ⟨hal-03749353⟩
- Karim Aissou, Hana Bouzit, Felix Krusch, Jean-Pierre Mericq, Didier Cot, et al.. Asymmetric Solvent-Annealed Triblock Terpolymer Thick Films Topped by a Hexagonal Perforated Lamellar Nanostructure. Macromolecular Rapid Communications, 2022, 43, pp.2100585. ⟨10.1002/marc.202100585⟩. ⟨hal-03419294⟩
- Sangho Lee, Ashwanth Subramanian, Nikhil Tiwale, Kim Kisslinger, Muhammad Mumtaz, et al.. Resolving Triblock Terpolymer Morphologies by Vapor-Phase Infiltration. Chemistry of Materials, 2020, 32 (12), pp.5309-5316. ⟨10.1021/acs.chemmater.0c01647⟩. ⟨hal-03040132⟩
- Mitica Cezar Spiridon, Nils Demazy, Cyril Brochon, Eric Cloutet, Georges Hadziioannou, et al.. Optical Alignment of Si-Containing Nanodomains Formed by Photoresponsive Amorphous Block Copolymer Thin Films. Macromolecules, 2020, ⟨10.1021/acs.macromol.9b01551⟩. ⟨hal-02429692⟩
- Karim Aissou, Muhammad Mumtaz, Hana Bouzit, Gilles Pécastaings, Giuseppe Portale, et al.. Bicontinuous Network Nanostructure with Tunable Thickness Formed on Asymmetric Triblock Terpolymer Thick Films. Macromolecules, 2019, 52 (12), pp.4413-4420. ⟨10.1021/acs.macromol.9b00572⟩. ⟨hal-02199632⟩
- Sangho Lee, Li-Chen Cheng, Kevin G. Yager, Muhammad Mumtaz, Karim Aissou, et al.. In Situ Study of ABC Triblock Terpolymer Self-Assembly under Solvent Vapor Annealing. Macromolecules, 2019, 52 (4), pp.1853-1863. ⟨10.1021/acs.macromol.8b02273⟩. ⟨hal-02323123⟩
- Yanyan Zhu, Karim Aissou, David Andelman, Xingkun Man. Orienting Cylinder-Forming Block Copolymer Thin Films: The Combined Effect of Substrate Corrugation and Its Surface Energy. Macromolecules, 2019, 52 (3), pp.1241-1248. ⟨10.1021/acs.macromol.8b02302⟩. ⟨hal-02323142⟩
- Ségolène Antoine, Karim Aissou, Muhammad Mumtaz, Gilles Pécastaings, Thierry Buffeteau, et al.. Nanoscale Archimedean Tilings Formed by 3‐Miktoarm Star Terpolymer Thin Films. Macromolecular Rapid Communications, 2019, 40 (7), pp.1800860. ⟨10.1002/marc.201800860⟩. ⟨hal-02199637⟩
- Karim Aissou, Muhammad Mumtaz, Nils Demazy, Gilles Pécastaings, Guillaume Fleury, et al.. Periodic Bicontinuous Structures Formed on the Top Surface of Asymmetric Triblock Terpolymer Thick Films. ACS Macro Letters, 2019, 8 (8), pp.923-930. ⟨10.1021/acsmacrolett.9b00403⟩. ⟨hal-02323100⟩
- Alberto Alvarez-Fernandez, Karim Aissou, Gilles Pécastaings, Georges Hadziioannou, Guillaume Fleury, et al.. High refractive index in low metal content nanoplasmonic surfaces from self-assembled block copolymer thin films. Nanoscale Advances, 2019, 1 (2), pp.849-857. ⟨10.1039/c8na00239h⟩. ⟨hal-01938227⟩
- Guillaume Fleury, Daniel Hermida-Merino, Dong Jingjin, Karim Aissou, Aleksei Bytchkov, et al.. Micellar-Mediated Block Copolymer Ordering Dynamics Revealed by In Situ Grazing Incidence Small-Angle X-Ray Scattering during Spin Coating. Advanced Functional Materials, 2019, 29 (10), pp.1806741. ⟨10.1002/adfm.201806741⟩. ⟨hal-02323201⟩
- Amira Kallel Elloumi, Imen Abdelhedi Abdelhedi Miladi, Anatoli Serghei, Daniel Taton, Karim Aissou, et al.. Partially Biosourced Poly(1,2,3-triazolium)-Based Diblock Copolymers Derived from Levulinic Acid. Macromolecules, 2018, 51 (15), pp.5820 - 5830. ⟨10.1021/acs.macromol.8b00962⟩. ⟨hal-01872202⟩
- Ségolène Antoine, Karim Aissou, Muhammad Mumtaz, Siham Telitel, Gilles Pecastaings, et al.. Core-Shell Double Gyroid Structure Formed by Linear ABC Terpolymer Thin Films. Macromolecular Rapid Communications, 2018, 39 (9), pp.1800043. ⟨10.1002/marc.201800043⟩. ⟨hal-01755261⟩
- Mitica Cezar Spiridon, Karim Aissou, Muhammad Mumtaz, Cyril Brochon, Eric Cloutet, et al.. Surface relief gratings formed by microphase-separated disperse red 1 acrylate-containing diblock copolymers. Polymer, 2018, 137, pp.378-384. ⟨10.1016/j.polymer.2018.01.032⟩. ⟨hal-01685087⟩
- Karim Aissou, Muhammad Mumtaz, Alberto Alvarez-Fernandez, Jean Mercat, Ségolène Antoine, et al.. Metallic Nanodot Patterns with Unique Symmetries Templated from ABC Triblock Terpolymer Networks. Macromolecular Rapid Communications, 2018, 39 (7), pp.1700754. ⟨10.1002/marc.201700754⟩. ⟨hal-01688010⟩
- Karim Aissou, Muhammad Mumtaz, Giuseppe Portale, Cyril Brochon, Eric Cloutet, et al.. Templated Sub-100-nm-Thick Double-Gyroid Structure from Si-Containing Block Copolymer Thin Films. Small, 2017, 13 (20), pp.1603777. ⟨10.1002/smll.201603777⟩. ⟨hal-01505528⟩
- Karim Aissou, Muhammad Mumtaz, Pierre Marcasuzaa, Cyril Brochon, Eric Cloutet, et al.. Highly Ordered Nanoring Arrays Formed by Templated Si-Containing Triblock Terpolymer Thin Films. Small, 2017, 13 (12), pp.1603184. ⟨10.1002/smll.201603184⟩. ⟨hal-01452668⟩
- Daniel Cordella, Farid Ouhib, Abdelhafid Aqil, Thomas Defize, Christine Jérome, et al.. Fluorinated Poly(ionic liquid) Diblock Copolymers Obtained by Cobalt-Mediated Radical Polymerization-Induced Self-Assembly. ACS Macro Letters, 2017, 6 (2), pp.121 - 126. ⟨10.1021/acsmacrolett.6b00899⟩. ⟨hal-01636939⟩
- Karim Aissou, Wonsang Kwon, Muhammad Mumtaz, Ségolène Antoine, Mireille Maret, et al.. Archimedean Tilings and Hierarchical Lamellar Morphology Formed by Semicrystalline Miktoarm Star Terpolymer Thin Films. ACS Nano, 2016, 10 (4), pp.4055-4061. ⟨10.1021/acsnano.5b06728⟩. ⟨hal-01369604⟩
- Karim Aissou, Muhammad Mumtaz, Özlem Usluer, Gilles Pecastaings, Giuseppe Portale, et al.. Anisotropic Lithium Ion Conductivity in Single-Ion Diblock Copolymer Electrolyte Thin Films . Macromolecular Rapid Communications, 2016, 37 (3), pp.221-226. ⟨10.1002/marc.201500562⟩. ⟨hal-01369626⟩
- Yecheol Rho, Karim Aissou, Muhammad Mumtaz, Wonsang Kwon, Gilles Pecastaings, et al.. Laterally Ordered Sub-10 nm Features Obtained From Directed Self-Assembly of Si-Containing Block Copolymer Thin Films. Small, 2015, 11 (48), pp.6377-6383. ⟨10.1002/smll.201500439⟩. ⟨hal-01361284⟩
- Karim Aissou, Muhammad Mumtaz, Guillaume Fleury, Giuseppe Portale, Christophe Navarro, et al.. Sub-10 nm Features Obtained from Directed Self-Assembly of Semicrystalline Polycarbosilane-Based Block Copolymer Thin Films. Advanced Materials, 2015, 27 (2), pp.261-265. ⟨10.1002/adma.201404077⟩. ⟨hal-01361353⟩
- Muhammad Mumtaz, Karim Aissou, Dimitrios Katsigiannopoulos, Cyril Brochon, Eric Cloutet, et al.. A well-defined polyelectrolyte and its copolymers by reversible addition fragmentation chain transfer (RAFT) polymerization: synthesis and applications . RSC Advances, 2015, 5 (119), pp.98559-98565. ⟨10.1039/c5ra19730a⟩. ⟨hal-01369646⟩
- Wubin Bai, Adam F. Hannon, Kevin W. Gotrik, Hong Kyoon Choi, Karim Aissou, et al.. Thin Film Morphologies of Bulk-Gyroid Polystyrene-block-polydimethylsiloxane under Solvent Vapor Annealing . Macromolecules, 2014, 47 (17), pp.6000-6008. ⟨10.1021/ma501293n⟩. ⟨hal-01369910⟩
- Joseph Kao, Seong-Jun Jeong, Zhang Jiang, Dong Hyun Lee, Karim Aissou, et al.. Direct 3-D Nanoparticle Assemblies in Thin Films via Topographically Patterned Surfaces . Advanced Materials, 2014, 26 (18), pp.2777-2781. ⟨10.1002/adma.201305561⟩. ⟨hal-01369750⟩
- Paul Coupillaud, Maréva Fèvre, Anne-Laure Wirotius, Karim Aissou, Guillaume Fleury, et al.. Precision Synthesis of Poly(Ionic Liquid)-Based Block Copolymers by Cobalt-Mediated Radical Polymerization and Preliminary Study of Their Self-Assembling Properties . Macromolecular Rapid Communications, 2014, 35 (4), pp.422-430. ⟨10.1002/marc.201300776⟩. ⟨hal-01369764⟩
- Salomé Tallegas, Thierry Baron, Guillaume Gay, Claire Aggrafeil, Billel Salhi, et al.. Block copolymer technology applied to nanoelectronics. Physica Status Solidi C: Current Topics in Solid State Physics, 2013, 10 (9), pp.1195-1206. ⟨10.1002/pssc.201300002⟩. ⟨hal-02114577⟩
- Simon Tricard, Yousuf Raza, Sandra Mazerat, Karim Aissou, Thierry Baron, et al.. Sequential growth of bistable copper-molybdenum coordination nanolayers on inorganic surfaces. Dalton Transactions, 2013, 42 (22), pp.8034-8040. ⟨10.1039/c3dt50259g⟩. ⟨hal-00926414⟩
- Karim Aissou, Andre Pfaff, Cristiano Giacomelli, Christophe Travelet, Axel H. E. Müller, et al.. Fluorescent Vesicles Consisting of Galactose-based Amphiphilic Copolymers with a pi-Conjugated Sequence Self-assembled in Water. Macromolecular Rapid Communications, 2011, 32 (12), pp.912-916. ⟨10.1002/marc.201100054⟩. ⟨hal-00951675⟩
- Karim Aissou, Issei Otsuka, Cyrille Rochas, Sébastien Fort, Sami Halila, et al.. Nano-Organization of Amylose- b -Polystyrene Block Copolymer Films Doped with Bipyridine. Langmuir, 2011, 27 (7), pp.4098-4103. ⟨10.1021/la104936k⟩. ⟨hal-02114617⟩
- Karim Aissou, Issei Otsuka, Cyrille Rochas, Sébastien Fort, Sami Halila, et al.. Nano-Organization of Amylose-b-Polystyrene Block Copolymer Films Doped with Bipyridine. Langmuir, 2011, 27 (7), pp.4098-4103. ⟨10.1021/la104936k⟩. ⟨hal-00951650⟩
- Cristiano Giacomelli, Vanessa Schmidt, Karim Aissou, Redouane Borsali. Block Copolymer Systems: From Single Chain to Self-Assembled Nanostructures. Langmuir, 2010, 26 (20), pp.15734-15744. ⟨10.1021/1a100641j⟩. ⟨hal-00950674⟩
- Issei Otsuka, Keita Fuchise, Sami Halila, Sébastien Fort, Karim Aissou, et al.. Thermoresponsive Vesicular Morphologies Obtained by Self-Assemblies of Hybrid Oligosaccharide-block-poly(N-isopropylacrylamide) Copolymer Systems. Langmuir, 2010, 26 (4), pp.2325-2332. ⟨10.1021/la902743y⟩. ⟨hal-00950666⟩
- Issei Otsuka, Keita Fuchise, Sami Halila, Sébastien Fort, Karim Aissou, et al.. Thermoresponsive Vesicular Morphologies Obtained by Self-Assemblies of Hybrid Oligosaccharide- block -poly( N -isopropylacrylamide) Copolymer Systems. Langmuir, 2010, 26 (4), pp.2325-2332. ⟨10.1021/la902743y⟩. ⟨hal-02114632⟩
- Karim Aissou, Martin Kogelschatz, Thierry Baron. Self-assembling study of a cylinder-forming block copolymer via a nucleation-growth mechanism. Nanotechnology, 2009, 20 (9), pp.art number 095602. ⟨10.1088/0957-4484/20/9/095602⟩. ⟨hal-00945185⟩
Communications dans un congrès
- Raphael Costes, Stéphane Badaire, Aurélie Achille, Karim Aissou, Damien Quemener, et al.. Exploring the potential of 2-vinylpyridine for the design of anion exchange membranes by plasma polymerization. 4ème réunion plénière de la FRH2, Oct 2024, La Grande Motte, France. ⟨hal-04790795⟩
- Thierry Baron, Claire Agraffeil, Florian Dhalluin, Martin Kogelschtaz, Gilles Cunge, et al.. Emerging Nanotechnology for integration of Nanostructures in Nanoelectronic devices. 2009 Advanced Research Workshop (FTM-6) Future Trends in Microelectronics: Unmapped Roads, 2009, Sardinia, Italy. ⟨10.1002/9780470649343.ch14⟩. ⟨hal-00461115⟩
Thèses
- Karim Aissou. Etude de l'auto-organisation de films minces de copolymères diblocs en vue d'applications pour la microélectronique. Matériaux. Université Joseph-Fourier - Grenoble I, 2008. Français. ⟨NNT : ⟩. ⟨tel-00267271⟩
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