Stefano Deabate a reçu son diplôme de « thèse » en chimie à l’Université de Turin, en Italie, en 1997. En 2001, il a obtenu son doctorat en chimie physique à l’Université de Montpellier II, Montpellier, France. Il a été, par la suite, en stage postdoctoral à Montpellier, jusqu’à ce qu’il devienne Maître de Conférences en 2003 à l’École National Supérieure de Chimie de Montpellier, où il enseigne en physico-chimie (spectroscopie vibrationnelle et électrochimie).
En tant que chercheur à l’Institut Européen des Membranes, son activité de recherche concerne les mécanismes de transport de masse/charge au sein de la matière condensée. Son travail comprend des matériaux pour le stockage (électrode de nickel) et la production électrochimique de l’énergie (électrolytes polymères pour piles à combustible basses températures). L’objectif de ses recherches est à la fois une meilleure compréhension des questions fondamentales et le développement de nouvelles méthodes de caractérisation par couplage de spectroscopie vibrationnelle in situ (IR et Raman) et mesures électrochimiques.
- Tél. : 04 67 14 91 12
- Courriel : stefano.deabate@umontpellier.fr
47 documents
Articles dans une revue
- Feihong Ren, Kun Qi, Jiefeng Liu, Patrice Huguet, Damien Voiry, et al.. Converting the Liquid Electrolyte of Li Batteries into a Catalyst for CO 2 RR via Laser Irradiation. ACS Applied Energy Materials, 2023, 6 (12), pp.6773-6780. ⟨10.1021/acsaem.3c00949⟩. ⟨hal-04171252⟩
- Thi Tran, Patrice Huguet, Arnaud Morin, Mike Robitzer, Stefano Deabate. Operando µ-Raman Measurement of the Water Distribution Along and Across the Membrane in the PEMFC. Journal of The Electrochemical Society, 2022, 169 (7), pp.10.1149/1945-7111/ac801e. ⟨10.1149/1945-7111/ac801e⟩. ⟨hal-03741451⟩
- Sabrine Zghal, Ilyes Jedidi, Marc Cretin, Sophie Annick Cerneaux, Didier Cot, et al.. Electroactive adsorbent composites of porous graphite carbon/carbon nanotube for highly efficient organic dye removal. Korean Journal of Chemical Engineering, 2022, ⟨10.1007/s11814-022-1119-y⟩. ⟨hal-03709791⟩
- Feihong Ren, Zhendong Li, Jiahe Chen, Patrice Huguet, Zhe Peng, et al.. Solvent–Diluent Interaction-Mediated Solvation Structure of Localized High-Concentration Electrolytes. ACS Applied Materials & Interfaces, 2022, 14 (3), pp.4211-4219. ⟨10.1021/acsami.1c21638⟩. ⟨hal-03709754⟩
- Nicola Precisvalle, Phuoc Hoang Ho, Thomas Cacciaguerra, Stefano Deabate, Luc Girard, et al.. Extra-framework zirconium clusters in metal organic framework DUT-67 controlled by the choice of the metal precursor. Microporous and Mesoporous Materials, 2021, 324, pp.111293. ⟨10.1016/j.micromeso.2021.111293⟩. ⟨hal-03448483⟩
- Thi Bich Hue Tran, Patrice Huguet, Arnaud Morin, Mike Robitzer, Stefano Deabate. Operando µ-Raman study of the membrane water content in the polymer electrolyte membrane fuel cell: Effects of gas flow-field geometry and temperature. Electrochimica Acta, 2021, 372, pp.137904. ⟨10.1016/j.electacta.2021.137904⟩. ⟨hal-03140599⟩
- M.V. Porozhnyy, S.A. Shkirskaya, D.Yu. Butylskii, V.V. Dotsenko, E.Yu. Safronova, et al.. Physicochemical and electrochemical characterization of Nafion-type membranes with embedded silica nanoparticles: Effect of functionalization. Electrochimica Acta, 2021, 370, pp.137689. ⟨10.1016/j.electacta.2020.137689⟩. ⟨hal-03709668⟩
- Feihong Ren, Zhendong Li, Yun Zhu, Patrice Huguet, Stefano Deabate, et al.. Artificial nucleation sites with stable SEI for Li metal anodes by aggressive Al pulverization. Nano Energy, 2020, 73, pp.104746. ⟨10.1016/j.nanoen.2020.104746⟩. ⟨hal-03483877⟩
- Alysson Duarte Rodrigues, Nathalie Marcotte, Françoise Quignard, Stefano Deabate, Mike Robitzer, et al.. Original synthesis and spectroscopic study of thiophene triazine derivatives with enhanced luminescence properties. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy [1994-..], 2020, 227, pp.117708. ⟨10.1016/j.saa.2019.117708⟩. ⟨hal-02433542⟩
- V. V. Kovalenko, V. Kotok, A. Sykchin, B. Ananchenko, A.V. Chernyad’ev, et al.. Al 3+ Additive in the Nickel Hydroxide Obtained by High-Temperature Two-Step Synthesis: Activator or Poisoner for Chemical Power Source Application?. Journal of The Electrochemical Society, 2020, 167 (10), pp.100530. ⟨10.1149/1945-7111/ab9a2a⟩. ⟨hal-02924352⟩
- V. A. Kotok, V.L. Kovalenko, P.V. Kovalenko, V.A. Solovov, S. Deabate, et al.. Electrochemical template synthesis of advanced Ni(OH)2/PVA films for electrochromic devices. Journal of Engineering and Applied Sciences, 2017, 12 (13), pp.3962. ⟨hal-01930745⟩
- Zhe Peng, Vasilica Badets, Patrice Huguet, Arnaud Morin, Pascal Schott, et al.. Operando μ -Raman study of the actual water content of perfluorosulfonic acid membranes in the fuel cell. Journal of Power Sources, 2017, 356, pp.200 - 211. ⟨10.1016/j.jpowsour.2017.04.095⟩. ⟨hal-01674797⟩
- M. Porozhnyy, V. V. Sarapulova, N. D. Pismenskaya, P. Huguet, S. Deabate, et al.. Mathematical modeling of concentration dependences of electric conductivity and diffusion permeability of anion-exchange membranes soaked in wine. Neftekhimiya / Petroleum Chemistry, 2017, 57 (6), pp.511 - 517. ⟨10.1134/S0965544117060081⟩. ⟨hal-01675212⟩
- V.L. Kovalenko, V. A. Kotok, A.A. Sykchin, A. V. Mudryi, B. A. Ananchenko, et al.. Nickel hydroxide obtained by high-temperature two-step synthesis as an effective material for supercapacitor applications. Journal of Solid State Electrochemistry, 2016, ⟨10.1007/s10008-016-3405-2⟩. ⟨hal-01476339⟩
- Marie Goletti Mbouga Nguemtchouin, Martin Benoît Ngassoum, Richard Kamga, Stefano Deabate, Serge Lagerge, et al.. Characterization of inorganic and organic clay modified materials: An approach for adsorption of an insecticidal terpenic compound. Applied Clay Science, 2015, 104, pp.110 - 118. ⟨10.1016/j.clay.2014.11.016⟩. ⟨hal-01682923⟩
- S. Deabate, P. Huguet, A. Morin, G. Gébel, Y. Lanteri, et al.. Raman Microspectroscopy as a Useful Tool for In Situ and Operando Studies of Water Transport in Perfluorosulfonic Membranes for PEMFCs. Fuel Cells, 2014, 14 (5), pp.677 - 693. ⟨10.1002/fuce.201300236⟩. ⟨hal-01687435⟩
- S. Deabate, Laure Gourrier, Thierry Michel, P. Huguet, Jean-Louis Bantignies, et al.. In situ mu-Raman spectroscopy study of an isolated micrometer-size pseudo-single crystal of beta-H2NiO2 under electrochemical operation. Applied Bionics and Biomechanics, 2014, 20 (4), pp.593-599. ⟨10.1007/s11581-014-1102-7⟩. ⟨hal-01202118⟩
- A. Peng, A. Morin, P. Huguet, Y. Lanteri, S. Deabate. Asymmetric bi-layer PFSA membranes as model systems for the study of water management in the PEMFC. Physical Chemistry Chemical Physics, 2014, 16 (38), pp.20941 - 20956. ⟨10.1039/c4cp02777a⟩. ⟨hal-01687563⟩
- R. Ghalloussi, W. Garcia-Vasquez, L. Chaabane, L. Dammak, C. Larchet, et al.. Ageing of ion-exchange membranes in electrodialysis: A structural and physicochemical investigation. Journal of Membrane Science, 2013, 436, pp.68 - 78. ⟨10.1016/j.memsci.2013.02.011⟩. ⟨hal-01689519⟩
- Z. Peng, P. Huguet, S. Deabate, A. Morin, A. Sutor. Depth-resolved micro-Raman spectroscopy of tri-layer PFSA membrane for PEM fuel cells: how to obtain reliable inner water contents. Journal of Raman Spectroscopy, 2013, 44 (2), pp.321 - 328. ⟨10.1002/jrs.4192⟩. ⟨hal-01689550⟩
- A. Sutor, P. Huguet, A. Morin, G. Gebel, Ts. Le, et al.. Influence of Compressive Stress on the Water Content of Perfluorosulphonated Membranes: A μ-Raman Study. Fuel Cells, 2012, 12 (2), pp.162 - 168. ⟨10.1002/fuce.201100053⟩. ⟨hal-01690609⟩
- Stefano Deabate, Gérard Gebel, Patrice Huguet, Arnaud Morin, Gerald Pourcelly. 3 In situ and operando determination of the water content distribution in proton conducting membranes for fuel cells: a critical review. Energy & Environmental Science, 2012, 5 (10), ⟨10.1039/c2ee21834h⟩. ⟨hal-01690640⟩
- Patrick Hermet, Laure Gourrier, Jean-Louis Bantignies, D. Ravot, Thierry Michel, et al.. Dielectric, magnetic, and phonon properties of nickel hydroxide. Physical Review B: Condensed Matter and Materials Physics (1998-2015), 2011, 84 (23), pp.235211. ⟨10.1103/PhysRevB.84.235211⟩. ⟨hal-00658214⟩
- Laure Gourrier, Stefano Deabate, Thierry Michel, Matthieu Paillet, Patrick Hermet, et al.. Characterization of Unusually Large “Pseudo-Single Crystal” of β-Nickel Hydroxide. Journal of Physical Chemistry C, 2011, 115 (30), pp.15067 - 15074. ⟨10.1021/jp203222t⟩. ⟨hal-01693500⟩
- P. Huguet, A. Morin, G. Gebel, S. Deabate, A.K. Sutor, et al.. In situ analysis of water management in operating fuel cells by confocal Raman spectroscopy. Electrochemistry Communications, 2011, 13 (5), pp.418 - 422. ⟨10.1016/j.elecom.2011.02.008⟩. ⟨hal-01695806⟩
- Jean-Louis Bantignies, Stefano Deabate, Ariette Righi, Stéphane Rols, Patrick Hermet, et al.. New insights in the vibrational behaviour of nickel hydroxide and oxyhydroxide using Inelastic Neutron Scattering, Far/Mid-Infrared and Raman Spectroscopies. Journal of Physical Chemistry C, 2008, 112 (6), pp.2193. ⟨10.1021/jp075819e⟩. ⟨hal-00287976⟩
- S. Deabate, R. Fatnassi, P. Sistat, P. Huguet. "In situ confocal-Raman measurement of water and methanol concentration profiles in Nafion (R) membrane under cross-transport conditions". Journal of Power Sources, 2008, 176 (1), pp.39-45. ⟨10.1016/j.jpowsour.2007.10.044⟩. ⟨hal-00362133⟩
- L. Grosmaire, S. Castagnoni, P. Huguet, P. Sistat, M. Boucher, et al.. "Probing proton dissociation in ionic polymers by means of in situ ATR-FTIR spectroscopy". Physical Chemistry Chemical Physics, 2008, 10, pp.1577-1583. ⟨10.1039/B714870D⟩. ⟨hal-00273855⟩
- Stefano Deabate, Fabrice Fourgeot, Francois Henn. Electrochemical behaviour of the β(II)-Ni(OH)2/β(III)-NiOOH redox couple upon potentiodynamic cycling conditions. Electrochimica Acta, 2006, 51 (25), pp.5430-5437. ⟨10.1016/j.electacta.2006.02.012⟩. ⟨hal-00186904⟩
- P. Huguet, P. Sistat, S. Deabate, E. Petit. "In-situ confocal-Raman imagery of ion and solvent transport through an ion-exchange membrane". Desalination, 2006, 200 (1-3), pp.57-58. ⟨10.1016/j.desal.2006.03.285⟩. ⟨hal-00273906⟩
- Francois Henn, Stefano Deabate. Structural modifications and electrochemical behaviour of the beta(II)-Ni(OH)(2)/beta(III)-NiOOH redox couple upon galvanostatic charging/discharging cycling. Electrochimica Acta, 2005, 50 (14), pp.2823-2835. ⟨10.1016/j.electacta.2004.11.030⟩. ⟨hal-00180063⟩
Communications dans un congrès
- Fan Ren, P Huguet, S. Deabate. Artificial nucleation sites and the study of solvation structures in electrolytes for lithium metal batteries. 4th Balard Chemistry Conference, Jun 2021, Montpellier, France. ⟨hal-03761611⟩
- Fan Ren, Patrice Huguet, S. Deabate. The Raman spectroscopy study on carbonate-based electrolyte for lithium metal batteries. International Congress on Energy and Engineering (ICECE-2021), Jun 2021, Chengdu, China. ⟨hal-03761592⟩
- V.L. Kovalenko, V. A. Kotok, A. S. Sykchin, B. A. Ananchenko, A. A. Burkov, et al.. Influence of crystallinity on -Ni(OH)2 electrochemical properties in the alkaline secondary cells and hybrid supercapacitors,. IX Ukrainian Congress on Electrochemistry, 2021, Kiev, Ukraine. ⟨hal-03785943⟩
- Feihong Ren, Zhendong Li, Yun Zhu, Patrice Huguet, Stefano Deabate, et al.. Artificial nucleation sites with stable SEI for Li metal anodes by aggressive Al pulverization. 8th Mediterranean Day of Young Researcher (JMJC 2020), Nov 2020, Toulon, France. ⟨hal-03775739⟩
- Thi Bich Hue Tran, Stefano Deabate, Patrice Huguet. Operando study of the actual hydration of the PEMFC membrane by Raman confocal spectroscopy: effect of the gas flow-field design. 67th Annual Meeting of the International Society of Electrochemistry, Aug 2016, La Haye, Netherlands. ⟨hal-01708450⟩
- Thi Bich Hue Tran, Stefano Deabate, Patrice Huguet. Effect of the gas flow-field design on the actual hydration of the PEMFC membrane: an operando study by micro-Raman spectroscopy. PERMEA 2016: Membrane Science and Technology Conference of the Viségrad Countries, May 2016, Prague, Czech Republic. ⟨hal-01708452⟩
- M. Cretin, S. Deabate, P. Huguet. In situ Raman microspectroscopy : a new tool to probe the actual water content of PFSA membranes in the working fuel cell. 41st International Conference on Ion Transport in Organic and Inorganic Membranes, May 2015, Sochi, Russia. ⟨hal-01714074⟩
- S. Deabate, P. Huguet, A. Morin, Z. Peng, V. Lates, et al.. Water transport properties of PFSA membranes investigated by in situ and operando RAMAN microspectroscopy: relationships with the FC performances. 6th International Conference on Fundamentals and Developments of Fuel Cells, Feb 2015, Toulouse, France. ⟨hal-01714078⟩
- G. Pourcelly, P. Sistat, P. Huguet, S. Lacour, S. Deabate, et al.. "Ion exchange membraes and associated processes. A state of the art and new trends". PERMEA 2007, September 2-6, 2007, Sep 2007, Siofok, Hungary. ⟨hal-00202946⟩
- S. Deabate, F. Fourgeot, F. Henn. Oral : "On the fundamental mechanisms involved in the electrochemical reactivity of the beta(II)-Ni(OH)2/beta(III)-NiO(OH) redox couple : solid state proton transfer and structural modifications". 207th Meeting of the Electrochemical Society - May, 15-20, 2005, 2005, Québec, Canada. ⟨hal-00081774⟩
- S. Deabate, N. Pismenskaia, E. Volodina, P. Sistat. Oral : "Effect of current density on the boundary diffusion layer thickness in an ion exchange system". 207th Meeting of the ElectroChemical Society - May 15-20, 2005, 2005, Québec, Canada. ⟨hal-00083186⟩
- S. Roualdes, L. Durivault, S. Deabate, J. Durand. Oral : "Plasma polymerized anion-exchange membranes for miniature alkaline fuel cells". 15th International Colloquium on Plasma Processes - June 5-9, 2005, 2005, Autrans, France. ⟨hal-00083103⟩
- S. Roualdes, L. Durivault, S. Deabate, J. Durand. Oral : "New class of anion-exchange membranes for miniature alkaline fuel cells". International Congress on Membranes and Membrane Processes - August 21-26, 2005, 2005, Seoul, South Korea. ⟨hal-00083625⟩
Ouvrages (y compris édition critique et traduction)
- V.L. Kovalenko, V. A. Kotok, A. S. Sykchin, B. A. Ananchenko, A. A. Burkov, et al. (Dir.). Influence of crystallinity on -Ni(OH)2 electrochemical properties in the alkaline secondary cells and hybrid supercapacitors, Electrohemistry of today: achievements, problems and prospects. 2021. ⟨hal-03784728⟩
Autres publications
- P. Huguet, P. Sistat, S. Deabate, E. Petit. Acte de Congrès : "In situ confocal-RAMAN imagery of ion and solvent transport through an ion-exchange membrane". 2006. ⟨hal-00128296⟩
Habilitations à diriger des recherches
- Stefano Deabate. Sur l’apport de la spectroscopie vibrationnelle in situ et operando à la compréhension des mécanismes de fonctionnement des matériaux ioniques pour le stockage et la production électrochimiques de l’énergie. Matériaux. Université de Montpellier, 2020. ⟨tel-04820884⟩
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